Mansur, oak ridge national laboratory scne workshop on. Because iascc accelerates the deterioration of various reactor components, it is imperative that it be understood and modeled to maintain reactor safety. Insitu tem irradiation experiments suggest that laserpeened 304 steels suffer less radiation damage than the untreated samples because the generated dislocation networks and twin boundaries serve as sinks for the annihilation of irradiation defects. There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2 sinduced scc. Fracture of irradiated austenitic stainless steel with. May 10, 2016 this report summarizes work performed at argonne national laboratory on irradiation assisted stress corrosion cracking iascc of austenitic stainless steels that were irradiated in the halden reactor in simulation of irradiation induced degradation of boiling water reactor bwr core internal components. The resistance to stress corrosion cracking is very dependent on metal susceptibility to ignition processes. As deduced in the preced ing sections, the electrochemical potential of stainless steel increased significantly on irradiation in oxy genated water but decreased slightly in the hydrogen treated water.
Environmental cracking or environmentally assisted cracking eac is the cracking of a material wherein an interaction with its environment is a causative factor in conjunction with tensile stress authors note. Two kinds of material degradation phenomena, namely, irradiation assisted stress corrosion cracking iascc and intergranular stress corrosion cracking igscc for the irradiated, nonsensitized sss and the nonirradiated, thermally sensitized sss, respectively in water environment are known, although their behaviors are similar to each other. The article addresses the effects of various radiation factors on corrosion. The elevated susceptibility to scc in irradiated materials, commonly referred to as irradiationassisted stress corrosion cracking iascc, is a complex phenomenon that involves simultaneous actions of irradiation, stress, and corrosion. Intergranular stress corrosion cracking was enhanced in the former case but did not occur in the latter. Irradiation assisted stress corrosion cracking iascc is a complicated phenomenon that poses a difficult problem for designers and operators of nuclear plants. What is the abbreviation for irradiation assisted stress corrosion cracking. Although fatigue is a degradation mechanism that is second in importance to radiation. Irradiation assisted stress corrosion cracking of austenitic stainless steel wwer reactor core internals anna hojna nuclear research institute rez, czech republic. It summarizes the overall trends and correlations for irradiationassisted stresscorrosion cracking. Irradiationassisted stresscorrosion cracking in austenitic. Mechanism of irradiation assisted stress corrosion crack. However, this discussion will focus on the normal usage of the term as defined below. For example, flow accelerated corrosion fac, corrosion fatigue cf, and irradiationassisted.
Irradiation assisted stress corrosion cracking iascc is a form of intergranular stress corrosion cracking igscc that has occurred infrequently during the last two decades in incore components. Irradiation assisted stress corrosion cracking iascc occurs above a critical neutron fluence in lightwater reactor lwr water environments at 288 c, but very little information exists to indicate susceptibility as temperatures are reduced. Shack abstract this report summarizes work performed at argonne national laboratory on irradiation assisted stress. This report summarizes work performed at argonne national laboratory on irradiationassisted stress corrosion cracking iascc of austenitic stainless steels that were irradiated in the halden reactor in simulation of irradiationinduced degradation of boiling water reactor bwr core internal components. Assessment of initial test conditions for experiments to. In addition, preliminary mechanism studies were performed to determine the cause of iascc in alloy x750. Irradiationassisted stress corrosion cracking iascc. Environmental cracking refers to a corrosion cracking caused by a combination of conditions that can specifically result in one of the following form of corrosion damage.
The irradiationassisted stress corrosion cracking iascc. Irradiation assisted stress corrosion cracking and grain. Stresses that cause environmental cracking arise from residual cold work, welding, grinding, thermal. Sep 01, 2011 abstract irradiation assisted stress corrosion cracking iascc refers to the processes by which irradiation enhances the inherent susceptibility of alloys to stress corrosion cracking scc. Following irradiation, the material was very susceptible to iascc.
Irradiation assisted stress corrosion cracking of hth. While irradiation is believed to accelerate corrosion of most components in the core, the components initially observed to crack prematurely were primarily small components bolts, springs, etc. Nickelbase alloys 625plus and 725 have exhibited good resistance to corrosion and stress corrosion cracking scc, however, limited data exists on their susceptibility to irradiation assisted stress corrosion cracking iascc in a boiling water reactor bwr environment. The relatively poor performance of alloy 600 in pwr primary water with regard to intergranular stress corrosion cracking and also with analogous higher strength alloys in the absence of irradiation suggests a different mechanism of cracking to that relevant to stainless steels. In recent years, failures of reactor internal components have been observed after the components have reached neutron fluence levels 5 x 10 20 ncm2 e 1 mev. Irradiationassisted,stress corrosion cracking iascc of austenitic stainless steel ss is known to occur in water environments at temperatures near 288c, but very little information exists to indicate susceptibility as temperatures are reduced.
Internal components of nuclear reactor pressure vessels are fabricated primarily from austenitic stainless steels because of their relatively high strength. This study investigates the deformation behaviour of a newly developed highstrength lowalloy mg alloy. Irradiationassisted stress corrosion cracking considerations. Stress corrosion cracking scc is an important degradation mechanism for. Micromechanistic origin of irradiationassisted stress corrosion cracking. The interaction of corrosion fatigue and stresscorrosion. The general pattern of the observed failures indicates that as nuclear plants age and fluence increases, various apparently nonsensitized austenitic. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack. Irradiation assisted stress corrosion cracking of commercial and. The required tensile stresses may be in the form of directly applied stresses or in the form of residual.
Irradiation has a profound effect on the stress corrosion cracking propensity of austenitic alloys in hightemperature water. Stress assisted corrosion is a type of corrosion that can occur in metals due to elevated static tensile stress levels. Localized deformation as a primary cause of irradiation assisted stress corrosion cracking. Because cracking susceptibility depends on many factors, such as alloy composition and microstructure, stress, radiation, and the environment, the failure mechanism has been termed irradiation assisted stress corrosion cracking iascc.
Aug 01, 2018 environmental cracking refers to a brittle fracture of a typical ductile material where the environments corrosive effect is the actual causing agent. Mar 04, 2020 such cracks have been seen in a number of internal components in boiling water reactors bwrs. Irradiationassisted stress corrosion cracking, corrosion. Stresscorrosion cracking, materials performance and. Such cracks have been seen in a number of internal components in boiling water reactors bwrs. Irradiationassisted stress corrosion cracking and impact.
Micromechanistic origin of irradiationassisted stress corrosion. Phenomenon of irradiation assisted stress corrosion. Irradiationinduced stress corrosion cracking of austenitic stainless steels. Initiation stress threshold irradiation assisted stress. Sac is a major concern for kraft recovery boilers in the pulp and paper industry as any water leak into the furnace can cause a smeltwater explosion in the boiler. Slow strain rate and crack growth rate tests were performed in the water. Application to fusion and generationiv fission reactors washington, dc. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Irradiation assisted stress corrosion cracking behavior of austenitic stainless steels applicable to lwr core internals by h. In the solution annealed, unirradiated condition, the stainless steel was resistant to stress corrosion cracking. Irradiationassisted stress corrosion cracking of austenitic. The earliest incidents of irradiation assisted stress corrosion cracking iascc in bwrs occurred during the early 1960s and were associated with cracking of type 304 stainless steel fuel cladding, where the driving forces for cracking were the increasing tensile hoop stress in the cladding due to the swelling fuel and the highly oxidizing conditions in the water.
Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. We use cookies to offer you a better experience, personalize content, tailor advertising, provide social media features, and better understand the use of our services. Irradiation assisted stress corrosion cracking iascc refers to intergranular stress corrosion cracking that is accelerated under the action of irradiation in light water reactor core components. During stress corrosion cracking, the material is relatively unattacked by the corrosive agent, but fine cracks form within it. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. Cracking corrosion is caused by various conditions that can result in different forms of corrosion damage like. Field experience as well as laboratory test results are considered to illustrate how iascc already impacts plant operation. This type of failure is known as stress corrosion cracking, often abbreviated to scc. Liquid metal crackinglmc, usually a physicochemical process. Abstract this work deals with the study of the irradiation assisted stress corrosion cracking and presents a methodology coupling microstructure, strain field and cracks initiation analysis. Irradiation assisted stress corrosion cracking iascc is a problem of growing importance in pressurized water reactors pwr. The effect of irradiation on stress corrosion cracking susceptibility and fracture toughness of alloy x750 has been investigated. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Irradiationassisted stress corrosion cracking as a factor.
Numerous studies have shown that the degree of intergranular stress corrosion cracking increases with dose. Unfortunately, the costs and dangers of gathering data on radiation effects are. These mechanisms can act individually or act in combination to accelerate the aging processes. Stress corrosion cracking tests show that transgranular cracks propagate in the untreated 304. Phd microstructural investigation of irradiation assisted. The premature cracking of an alloy in the presence of a. The factors which influence degradation of these parts are. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Irradiation assisted, stress corrosion cracking iascc of austenitic stainless steel ss is known to occur in water environments at temperatures near 288c, but very little information exists to indicate susceptibility as temperatures are reduced. Stress corrosion cracking will usually cause the material to fail in a brittle manner, which can have grave consequences as there is usually little or no warning before the failure occurs.
Bruemmer b a departments of nuclear engineering and materials science and engineering, university of michigan, ann arbor, mi 48109, usa b pacific northwest laboratory, richland, wa 993. Irradiationassisted stress corrosion cracking behavior of austenitic stainless steels applicable to lwr core internals. Nuclear engineering and design 181 1998 5560 irradiation assisted stress corrosion cracking m. Stressassisted corrosion in boiler tubes technical report. One common misconception is that scc is the result of stress concentration at corrosion. The paper aims to give a present status of knowledge on irradiationassisted stress corrosion cracking iascc from the point of view of nuclear power plant life extension. Current understanding of radiationinduced degradation in. This new second edition serves as a goto reference on the complex subject of stress corrosion cracking scc, offering information to help metallurgists, materials scientists, and designers determine whether scc will be an issue for their design or application.
It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Effects of irradiation on corrosion and environmentally. Irradiation assisted stress corrosion cracking iascc has been well documented both in the laboratory and in service over the past two decades. For example, flow accelerated corrosion fac, corrosion fatigue cf, and irradiationassisted stress corrosion cracking iascc can act in combination with each other to magnify their individual effect. Irradiation assisted stress corrosion cracking request pdf. Irradiationassisted stress corrosion cracking behavior of.
A mechanistic basis for irradiation assisted stress. Effects of irradiation on intergranular stress corrosion cracking. This article begins with an introduction to the iascc problem experienced in light water reactors, followed by a summary of existing plant and laboratory data that reveal its dependence on irradiation. Stress corrosion cracking is a phenomenon where a synergistic action of corrosion and tensile stress leads to brittle fracture of normally ductile materials at generally lower stress levels. Effect of irradiation on stresscorrosion cracking and. The iascc is a term used for stress corrosion crack ing of structural materials appearing after irradiation.
Study of the effect of swelling on irradiation assisted. Irradiation assisted stress corrosion cracking of austenitic. Irradiation assisted stress corrosion cracking iascc. Effects of irradiation on intergranular stress corrosion. Irradiationassisted stress corrosion cracking osti. Effects of irradiation on intergranular stress corrosion cracking g. It is referred to as assisted because irradiation enhances, or accelerates the igscc process over the unirradiated state. A mechanistic basis for irradiation assisted stress corrosion cracking. Thirteen alloys including high and lowstrength nickelbase alloys, austenitic stainless steels, and ferritic alloys were irradiated using 2 mev protons to a.
Role of irradiated microstructure and microchemistry in. Field experience as well as laboratory test results are considered to illustrate how iascc. Auger analysis and corrosion testing indicated that the irradiated material was no longer free of grain boundary segregation. Irradiation assisted stress corrosion cracking iascc is a potential failure mode suffered by the corecomponents of austenitic stainless steels in the aged lightwater reactor lwr, which is the intergranular type cracking caused by synergistic effects of neutrongamma radiation and chemical environment. This paper deals with fracture of neutron irradiated austenitic tistabilized stainless steel 08ch18n10t. Failure mechanisms of irradiated zr alloys related to pci. Stress corrosion cracking and corrosion of candidate. Irradiation assisted stress corrosion cracking iascc is an intergranular cracking effect which can occur in heavily irradiated internal structural components of nuclear reactor cores. Irradiation in high temperature water generally accelerates both general corrosion and stress corrosion cracking. Abstract the paper aims to give a present status of knowledge on irradiation assisted scc iascc from the point of view of nuclear power plant life extension. Stress corrosion is a form of galvanic corrosion, where stressed areas of the material. Irradiationassisted stress corrosion cracking iascc is a form of intergranular stress corrosion cracking igscc that has occurred infrequently during the last two decades in incore components of nonsensitized austenitic stainless steel. Liquid metal cracking lmc, usually a physicochemical process.
The irradiationassisted stress corrosion cracking iascc issue. Irradiation assisted corrosion and stress corrosion. A corrosive medium especially chloridebearing or hydrogensulphide h 2 s media. Irradiationinduced stress corrosion cracking of austenitic. Stress corrosion cracking and corrosion of candidate alloys for the supercritical water reactor concept. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment.
Irradiation assisted stress corrosion cracking of hth alloy x750 and alloy 625. The impact of irradiation damage accumulated in fuel claddings on their mechanical behavior and their susceptibility to iodineinduced stress corrosion cracking iscc was studied in irradiated zirconium and standard zircaloy4 sheets subjected to interrupted tension tests in methanoliodine solutions and in an inert environment. Quantitative prediction of environmentally assisted cracking. Potential lowtemperature behavior is assessed based on the temperature dependencies of intergranular ig scc in the absence of irradiation, radiation. Irradiationassisted stresscorrosion cracking iascc is a complicated phenomenon that poses a difficult problem for designers and operators of nuclear plants. Irradiationassisted stress corrosion cracking behavior. Irradiation assisted stress corrosion cracking and impact. Stress assisted corrosion sac of carbon steel boiler tubes is one of the major causes of waterside failure in industrial boilers. The steel had been tested in air and in water environment 320c using several tests representing different stress strain conditions for crack initiation and growth.
Understanding the impact of radiation corrosion on. The effects of increased exposure to irradiation, stress, andor coolant can substantially increase susceptibility to stress corrosion cracking of austenitic steels in hightemperature water environments. An understanding of the mechanism s of iascc is required in order to provide guidance for the development of mitigation strategies. Stress corrosion cracking of neutron irradiated cast stainless steels. Irradiationassisted stress corrosion cracking iascc is a form of intergranular stress corrosion cracking igscc that has occurred infrequently during the last two decades in incore components. Environmental cracking can occur with a wide variety of metals and alloys and includes all of the types of corrosion failures listed below. It has, however, been found to undergo irradiation assisted stress corrosion cracking iascc, though the exact mechanism governing the increased cracking susceptibility is not well understood.
Mechanism of irradiation assisted stress corrosion crack initiation in thermally sensitized 304 stainless steel author links open overlay panel t. Mechanism of dislocation channelinduced irradiation. The mechanism by which dislocation channeling induces irradiation assisted stress corrosion cracking was determined using fecr15ni austenitic stainless steel irradiated with protons to a dose of 5 dpa and strained at high temperature in both argon and simulated boiling water reactor normal water chemistry environments. Specifically, it is a stress attack directed at locations where applied or residual stresses are imparted to the metal. Shack nuclear engineering division argonne national laboratory, argonne, il 60439. Stress corrosion cracking tests show that transgranular cracks. Understanding the impact of radiation corrosion on irradiationassisted stress corrosion cracking elin toijer1. Iascc irradiation assisted stress corrosion cracking. Void swelling, effects of helium, and irradiation induced stress corrosion cracking roger e. The factors include radiationinduced segregation at grain boundaries, radiation hardening, mode of deformation, radiation creep relaxation, and radiolysis.
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